Caption: The figure shows aluminum clusters reacting with water to produce hydrogen. The image on the bottom depicts a water molecule (one hydrogen atom (red ball) and two oxygen atoms (silver balls)) splitting on the surface of an aluminum cluster. The blue regions are Lewis-acid sites and the orange regions are Lewis-base sites. The upper-right image shows multiple water molecules binding to the active sites of an aluminum cluster. The upper-left image shows the release of hydrogen (two silver balls surrounded by orange halo).
Scientists at Penn State
University and the Virginia Commonwealth University have discovered a way
to produce hydrogen by exposing selected clusters of aluminum atoms to
water. The findings are important because they demonstrate that it is the
geometries of these aluminum clusters, rather than solely their electronic
properties, that govern the proximity of the clusters' exposed active sites.
The proximity of the clusters' exposed sites plays an important role in
affecting the clusters' reactions with water. The team's findings will
be published in the 23 January 2009 issue of the journal Science.
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They found that a water
molecule will bind between two aluminum sites in a cluster as long as one
of the sites behaves like a Lewis acid, a positively charged center that
wants to accept an electron, and the other behaves like a Lewis base, a
negatively charged center that wants to give away an electron. The Lewis-acid
aluminum binds to the oxygen in the water and the Lewis-base aluminum dissociates
a hydrogen atom. If this process happens a second time with another set
of two aluminum sites and a water molecule, then two hydrogen atoms are
available, which then can join to become hydrogen gas (H2).
The team found that the aluminum clusters react differently when exposed to water, depending on the sizes of the clusters and their unique geometric structures. Three of the aluminum clusters produced hydrogen from water at room temperature. "The ability to produce hydrogen at room temperature is significant because it means that we did not use any heat or energy to trigger the reaction," said Khanna. "Traditional techniques for splitting water to produce hydrogen generally require a lot of energy at the time the hydrogen is generated. But our method allows us to produce hydrogen without supplying heat, connecting to a battery, or adding electricity. Once the aluminum clusters are synthesized, they can generate hydrogen on demand without the need to store it." Khanna hopes that the team's findings will pave the way toward investigating how the aluminum clusters can be recycled for continual usage and how the conditions for the release of hydrogen can be controlled. "It looks as though we might be able to come up with ways to remove the hydroxyl group (OH-) that remains attached to the aluminum clusters after they generate hydrogen so that we can reuse the aluminum clusters again and again," he said. The team plans to continue their research with a goal of refining their new method. This research was supported by the Air Force Office of Scientific Research. CONTACTS:
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